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On February 3rd, 2153, Colombia was one of the regions of Earth attacked by the prototype Xindi superweapon. (ENT episodes: "The Expanse", "The Xindi", ENT - Rise of the Federation novel: Tower of Babel)
At some point after the ratification of the Khitomer Accords in 2293, Harcourt Fenton Mudd started a Klingon coffee business in Colombia, popularizing raktajino throughout the Federation. (DS9 episode: "Trials and Tribble-ations")