The Orion chancellor is the leader of an Orion government.

In 2372, Kira Nerys wished the Orb of Wisdom had been found by the Orions rather than the Ferengi, as she felt the Bajorans could have made a deal with the Orion chancellor better than one with Grand Nagus Zek. (DS9 novel: The 34th Rule)

Heads of Government
Interstellar States	Federation President • Klingon Chancellor • Romulan Praetor • Imperial Romulan State Empress • Cardassian Castellan • Cardassian Chief Executor • Ferengi Grand Nagus • Tzenkethi Autarch • Gorn Imperator • Breen Domo • Orion Chancellor • Tholian Ruling Conclave • Thallonian Prime Minister • Tezwan Prime Minister • Enoch President • Kropasar High Cyning • Caeliar Tanwa-Seynorral • Talarian Commander-in-Chief • Knshaya Pontifex
Federation Member States	United Earth Prime Minister • Vulcan Administrator • Vulcan First Minister • Andorian Chancellor • Alpha Centauri Governor • Bajoran First Minister • Trill President • Cestus Governor • Betazoid Governor • Denevan President • Pacifican Governor • Peliar Zel Governor • Zaldan Leader
Federation Colonies	Tarsus Governor • Alpha V Governor • Mantilles Governor • Caldos Governor
UFP Member State Polities	United States President (United Earth) • Indian Prime Minister (United Earth) • Governor of Prophet's Landing (Republic of Bajor)
Mirror Universe	Terran Emperor • Terran Consul • Klingon Regent