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Numerous species used polaron-based weaponry and defensive systems, including:
- The Borg (VOY episode: "Scorpion")
- The Cheka (DS9 - Mission Gamma novel: This Gray Spirit)
- The Dominion (DS9 episode: "The Jem'Hadar")
- The Hierarchy (VOY episode: "Renaissance Man")
- The Nyrians (VOY episode: "Displaced")
- The Swarm (VOY episode: "The Swarm")
- The Varro (VOY episode: "The Disease")
They can also be utilized to interfere with such energy-emitting systems as shields, tractor beams, and magnetic confinement fields. (VOY episodes: "Extreme Risk", "Course: Oblivion", "Ashes to Ashes", "Future's End") Similarly, polarons can be used to enhance such systems. (VOY episodes: "Hunters", "The Void")