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Tobacco was a highly addictive, carcinogenic plant that was smoked on Earth until the 21st century. (DS9 episode: "Little Green Men") Tobacco could also be chewed for pleasure. Either medium released into the humanoid bloodstream the habit-inducing drug nicotine (DS9 novel: Antimatter)
The Capellan Markah plant had leaves similar to tobacco leaves, which were also dried and rolled into cigarillos. However unlike tobacco Markah cigarillos were neither toxic or addictive. (ST - The Fall novel: The Poisoned Chalice)